{"id":125480,"date":"2023-01-31T10:21:26","date_gmt":"2023-01-31T02:21:26","guid":{"rendered":"https:\/\/www.alpapowder.com\/125480\/"},"modified":"2023-01-31T10:21:27","modified_gmt":"2023-01-31T02:21:27","slug":"ung-dung-cua-gangue-than-trong-linh-vuc-vat-lieu-gom-day-dac","status":"publish","type":"post","link":"https:\/\/www.alpapowder.com\/vi\/125480\/","title":{"rendered":"\u1ee8ng d\u1ee5ng c\u1ee7a gangue than trong l\u0129nh v\u1ef1c v\u1eadt li\u1ec7u g\u1ed1m d\u00e0y \u0111\u1eb7c"},"content":{"rendered":"

\"\"<\/p>\n

Gangue than l\u00e0 \u0111\u00e1 b\u1ecb m\u1eafc k\u1eb9t trong v\u1ec9a than, v\u00e0 n\u00f3 c\u0169ng l\u00e0 ch\u1ea5t th\u1ea3i trong qu\u00e1 tr\u00ecnh khai th\u00e1c than v\u00e0 r\u1eeda than. Hi\u1ec7n nay, l\u01b0\u1ee3ng than \u0111\u00e1 t\u00edch l\u0169y trong n\u01b0\u1edbc l\u00ean t\u1edbi v\u00e0i t\u1ef7 t\u1ea5n, g\u00e2y thi\u1ec7t h\u1ea1i nghi\u00eam tr\u1ecdng cho m\u00f4i tr\u01b0\u1eddng sinh th\u00e1i. L\u00e0 m\u1ed9t ngu\u1ed3n t\u00e0i nguy\u00ean c\u00f3 th\u1ec3 t\u00e1i ch\u1ebf, gangue than \u0111\u00e3 \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng r\u1ed9ng r\u00e3i trong nhi\u1ec1u l\u0129nh v\u1ef1c.<\/p>\n

Qua nghi\u00ean c\u1ee9u, ng\u01b0\u1eddi ta th\u1ea5y r\u1eb1ng c\u00e1c th\u00e0nh ph\u1ea7n ch\u00ednh trong gangue than l\u00e0 alumina v\u00e0 silica<\/a>, v\u00e0 c\u00e1c h\u1ee3p ch\u1ea5t n\u00e0y th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng l\u00e0m nguy\u00ean li\u1ec7u th\u00f4 \u0111\u1ec3 s\u1ea3n xu\u1ea5t g\u1ed1m s\u1ee9. B\u1ea3n th\u00e2n gangue than c\u0169ng c\u00f3 m\u1ed9t s\u1ed1 l\u01b0\u1ee3ng l\u1edbn micropores v\u00e0 di\u1ec7n t\u00edch b\u1ec1 m\u1eb7t ri\u00eang cao. Do \u0111\u00f3, gangue than c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng \u0111\u1ec3 \u0111i\u1ec1u ch\u1ebf g\u1ed1m s\u1ee9 v\u00e0 c\u00e1c v\u1eadt li\u1ec7u kh\u00e1c v\u1edbi c\u00e1c \u0111\u1eb7c t\u00ednh tuy\u1ec7t v\u1eddi nh\u01b0 \u0111\u1ed9 b\u1ec1n c\u01a1 h\u1ecdc cao, kh\u1ea3 n\u0103ng ch\u1ed1ng \u0103n m\u00f2n axit v\u00e0 ki\u1ec1m v\u00e0 tu\u1ed5i th\u1ecd cao.<\/p>\n

1. Mullite d\u00e0y \u0111\u1eb7c v\u00e0 v\u1eadt li\u1ec7u composite c\u1ee7a n\u00f3<\/p>\n

Mullite (3Al2O3\u00b72SiO2) l\u00e0 v\u1eadt li\u1ec7u ch\u1ecbu l\u1eeda ch\u1ea5t l\u01b0\u1ee3ng cao v\u1edbi \u0111\u1eb7c t\u00ednh t\u1ef7 tr\u1ecdng cao, kh\u1ea3 n\u0103ng ch\u1ed1ng s\u1ed1c nhi\u1ec7t t\u1ed1t, kh\u1ea3 n\u0103ng ch\u1ed1ng d\u00e3o t\u1ed1t, h\u1ec7 s\u1ed1 gi\u00e3n n\u1edf th\u1ea5p v\u00e0 th\u00e0nh ph\u1ea7n h\u00f3a h\u1ecdc \u1ed5n \u0111\u1ecbnh. \u1ede n\u01b0\u1edbc t\u00f4i, c\u00f3 r\u1ea5t \u00edt tr\u1eef l\u01b0\u1ee3ng mullite t\u1ef1 nhi\u00ean v\u00e0 h\u1ea7u h\u1ebft mullite \u0111\u01b0\u1ee3c t\u1ed5ng h\u1ee3p nh\u00e2n t\u1ea1o. N\u00f3i chung, cao lanh v\u00e0 b\u1ed9t alumina \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng l\u00e0m nguy\u00ean li\u1ec7u th\u00f4, v\u00e0 v\u1eadt li\u1ec7u mullite \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf b\u1eb1ng c\u00e1ch thi\u00eau k\u1ebft ho\u1eb7c \u0111\u1ed1t \u0111i\u1ec7n. Do h\u00e0m l\u01b0\u1ee3ng kaolinite trong gangue than th\u01b0\u1eddng c\u00f3 th\u1ec3 \u0111\u1ea1t t\u1edbi h\u01a1n 90%, v\u1eadt li\u1ec7u composite mullite v\u00e0 mullite c\u00f3 hi\u1ec7u su\u1ea5t tuy\u1ec7t v\u1eddi c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf b\u1eb1ng c\u00e1ch tr\u1ed9n gangue v\u1edbi c\u00e1c v\u1eadt li\u1ec7u ph\u1ee5 tr\u1ee3 nh\u01b0 Al2O3 v\u00e0 nung \u1edf nhi\u1ec7t \u0111\u1ed9 cao. \u0111\u1ea5t n\u01b0\u1edbc t\u00f4i c\u0169ng \u0111\u00e3 \u0111\u1ea1t \u0111\u01b0\u1ee3c m\u1ed9t s\u1ed1 ti\u1ebfn b\u1ed9 trong vi\u1ec7c chu\u1ea9n b\u1ecb mullite v\u00e0 v\u1eadt li\u1ec7u composite c\u1ee7a n\u00f3 t\u1eeb gangue than \u0111\u00e1.<\/p>\n

S\u1eed d\u1ee5ng bauxite h\u00e0m l\u01b0\u1ee3ng nh\u00f4m cao l\u00e0m nguy\u00ean li\u1ec7u ch\u00ednh, c\u00f9ng v\u1edbi than \u0111\u00e1 v\u00e0 m\u1ed9t l\u01b0\u1ee3ng nh\u1ecf Al2O3 \u0111\u1ec3 \u0111i\u1ec1u ch\u1ebf clinker mullite, nghi\u00ean c\u1ee9u cho th\u1ea5y clinker mullite v\u1edbi hi\u1ec7u su\u1ea5t tuy\u1ec7t v\u1eddi c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c nung \u1edf 1700 \u00b0 C v\u00e0 \u0111\u1ed9 x\u1ed1p r\u00f5 r\u00e0ng c\u1ee7a n\u00f3 nh\u1ecf h\u01a1n 25 %, kh\u1ed1i l\u01b0\u1ee3ng ri\u00eang \u2265 2,75g\/cm3.<\/p>\n

Gangue ng\u00e2m than \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng l\u00e0m nguy\u00ean li\u1ec7u ch\u00ednh, \u0111\u01b0\u1ee3c tr\u1ed9n \u0111\u1ec1u v\u1edbi alumina v\u00e0 mullite \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf b\u1eb1ng c\u00e1ch thi\u00eau k\u1ebft tr\u1ea1ng th\u00e1i r\u1eafn. \u0110\u1ea7u ti\u00ean n\u00f3 s\u1ebd t\u0103ng l\u00ean v\u00e0 sau \u0111\u00f3 gi\u1ea3m nh\u1eb9, do \u0111\u00f3, th\u1eddi gian gi\u1eef \u0111\u1ec3 chu\u1ea9n b\u1ecb mullite ph\u1ea3i \u0111\u01b0\u1ee3c ki\u1ec3m so\u00e1t trong v\u00f2ng 2 gi\u1edd.<\/p>\n

S\u1eed d\u1ee5ng bauxite v\u00e0 than \u0111\u00e1 l\u00e0m nguy\u00ean li\u1ec7u ch\u00ednh, vanadi pentoxit (V2O5) v\u00e0 nh\u00f4m florua (AlF3) l\u00e0m ch\u1ea5t ph\u1ee5 gia, m\u1ed9t tinh th\u1ec3 c\u00f3 pha tinh th\u1ec3 ch\u00ednh l\u00e0 pha mullite \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf b\u1eb1ng ph\u1ea3n \u1ee9ng tr\u1ea1ng th\u00e1i r\u1eafn. Nghi\u00ean c\u1ee9u cho th\u1ea5y: khi nh\u00f4m Khi bauxite v\u00e0 silic-alumin trong gangue than \u0111\u01b0\u1ee3c tr\u1ed9n theo t\u1ef7 l\u1ec7 mol 2:3,05, \u0111\u1ed9 b\u1ec1n v\u00e0 \u0111\u1ed9 c\u1ee9ng c\u1ee7a v\u1eadt li\u1ec7u mullite \u0111\u00e3 chu\u1ea9n b\u1ecb \u0111\u00e3 \u0111\u01b0\u1ee3c c\u1ea3i thi\u1ec7n \u0111\u00e1ng k\u1ec3 v\u00e0 hi\u1ec7u su\u1ea5t l\u00e0 t\u1ed1t nh\u1ea5t. M\u1eadt \u0111\u1ed9 th\u1ec3 t\u00edch c\u1ee7a n\u00f3 cao t\u1edbi 2,3g\/cm3, \u0111\u1ed9 x\u1ed1p bi\u1ec3u ki\u1ebfn l\u00e0 23,6%, t\u1ef7 l\u1ec7 h\u1ea5p th\u1ee5 n\u01b0\u1edbc l\u00e0 10,55% v\u00e0 \u0111\u1ed9 b\u1ec1n u\u1ed1n l\u00e0 114MPa.<\/p>\n

V\u1eadt li\u1ec7u composite th\u1ee7y tinh silica<\/a> cao mullite \u0111\u00e3 \u0111\u01b0\u1ee3c t\u1ed5ng h\u1ee3p th\u00e0nh c\u00f4ng b\u1eb1ng c\u00e1ch s\u1eed d\u1ee5ng gangue than v\u00e0 cao lanh l\u00e0m nguy\u00ean li\u1ec7u th\u00f4 v\u00e0 th\u00eam fenspat kali. Nghi\u00ean c\u1ee9u cho th\u1ea5y nhi\u1ec7t \u0111\u1ed9 thi\u00eau k\u1ebft c\u1ee7a h\u1ed7n h\u1ee3p kh\u00f4ng th\u00eam kali fenspat l\u00e0 tr\u00ean 1590\u00b0C, trong khi nhi\u1ec7t \u0111\u1ed9 thi\u00eau k\u1ebft c\u1ee7a h\u1ed7n h\u1ee3p c\u00f3 t\u1ef7 l\u1ec7 K2O l\u00e0 1,5% v\u00e0 th\u00eam kali fenspat c\u00f3 th\u1ec3 gi\u1ea3m xu\u1ed1ng 1530\u00b0C. Do \u0111\u00f3, th\u00eam m\u1ed9t l\u01b0\u1ee3ng kali fenspat nh\u1ea5t \u0111\u1ecbnh v\u00e0o h\u1ed7n h\u1ee3p c\u00f3 th\u1ec3 l\u00e0m gi\u1ea3m nhi\u1ec7t \u0111\u1ed9 thi\u00eau k\u1ebft.<\/p>\n

S\u1eed d\u1ee5ng gangue than l\u00e0m nguy\u00ean li\u1ec7u th\u00f4, gangue \u0111\u01b0\u1ee3c k\u00edch ho\u1ea1t b\u1eb1ng c\u00e1ch lo\u1ea1i b\u1ecf t\u1ea1p ch\u1ea5t, nung v\u00e0 c\u00e1c quy tr\u00ecnh kh\u00e1c, v\u00e0 v\u1eadt li\u1ec7u b\u1ed9t h\u1ed7n h\u1ee3p nano-mullite \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf b\u1eb1ng qu\u00e1 tr\u00ecnh k\u1ebft tinh th\u1ee7y nhi\u1ec7t. K\u1ebft qu\u1ea3 cho th\u1ea5y pha composite nano-mullite \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf t\u1eeb b\u1ed9t than ho\u1ea1t t\u00ednh gangue trong \u0111i\u1ec1u ki\u1ec7n dung d\u1ecbch natri hydroxit n\u1ed3ng \u0111\u1ed9 2-4mol\/L, nhi\u1ec7t \u0111\u1ed9 khu\u1ea5y 80-90\u00b0C, th\u1eddi gian b\u1ea3o qu\u1ea3n nhi\u1ec7t 3h, v\u00e0 t\u1ef7 l\u1ec7 l\u1ecfng-r\u1eafn l\u00e0 10mL\/g. B\u1ed9t, b\u1ed9t h\u1ed7n h\u1ee3p nano-mullite c\u00f3 hi\u1ec7u \u1ee9ng k\u1ebft tinh t\u1ed1t, h\u1ea7u h\u1ebft l\u00e0 tinh th\u1ec3 c\u1ed9t, chi\u1ec1u d\u00e0i h\u1ea1t l\u00e0 50nm v\u00e0 t\u1ef7 l\u1ec7 khung h\u00ecnh trung b\u00ecnh \u0111\u1ea1t 3,5.<\/p>\n

2. Silon d\u00e0y \u0111\u1eb7c v\u00e0 v\u1eadt li\u1ec7u composite c\u1ee7a n\u00f3<\/p>\n

S\u1eed d\u1ee5ng gangue than nh\u00f4m cao, b\u1ed9t c\u00f4 \u0111\u1eb7c s\u1eaft v\u00e0 b\u1ed9t than c\u1ed1c l\u00e0m nguy\u00ean li\u1ec7u th\u00f4, v\u1eadt li\u1ec7u \u0111\u1eadm \u0111\u1eb7c h\u1ed7n h\u1ee3p Fe-Sialon \u0111\u01b0\u1ee3c \u0111i\u1ec1u ch\u1ebf b\u1eb1ng ph\u01b0\u01a1ng ph\u00e1p th\u1ea5m nit\u01a1 kh\u1eed nhi\u1ec7t \u1edf 1400-1550\u00b0C trong 4 gi\u1edd. Ng\u01b0\u1eddi ta th\u1ea5y r\u1eb1ng h\u00e0m l\u01b0\u1ee3ng than c\u1ed1c v\u01b0\u1ee3t qu\u00e1 10% 1. V\u1eadt li\u1ec7u \u0111\u1eadm \u0111\u1eb7c Fe-Sialon \u0111\u01b0\u1ee3c chu\u1ea9n b\u1ecb \u1edf 1500\u2103 trong 4 gi\u1edd c\u00f3 s\u1ef1 ph\u00e2n b\u1ed1 h\u1ea1t \u0111\u1ed3ng \u0111\u1ec1u nh\u1ea5t v\u00e0 hi\u1ec7u su\u1ea5t t\u1ed1t nh\u1ea5t.<\/p>\n

S\u1eed d\u1ee5ng gangue than v\u00e0 \u0111\u1ea5t s\u00e9t t\u1ef1 nhi\u00ean l\u00e0m nguy\u00ean li\u1ec7u ch\u00ednh, quy tr\u00ecnh \u0111\u00fac keo \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng \u0111\u1ec3 t\u1ea1o h\u00ecnh th\u00e2n m\u00e0u xanh l\u00e1 c\u00e2y v\u00e0 v\u1eadt li\u1ec7u g\u1ed1m d\u00e0y \u0111\u1eb7c h\u1ed7n h\u1ee3p \u03b2-Sialon\/SiC \u0111\u00e3 \u0111\u01b0\u1ee3c t\u1ed5ng h\u1ee3p th\u00e0nh c\u00f4ng b\u1eb1ng quy tr\u00ecnh th\u1ea5m nit\u01a1 kh\u1eed nhi\u1ec7t. Nghi\u00ean c\u1ee9u cho th\u1ea5y r\u1eb1ng quy tr\u00ecnh \u0111\u00fac keo \u0111\u01b0\u1ee3c t\u1ed1i \u01b0u h\u00f3a c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng \u0111\u1ec3 t\u1ea1o ra v\u1eadt th\u1ec3 m\u00e0u xanh l\u00e1 c\u00e2y v\u1edbi m\u1eadt \u0111\u1ed9 cao t\u1edbi 1,12g\/cm3 v\u00e0 v\u1eadt li\u1ec7u composite \u03b2-Sialon\/SiC \u0111\u1eadm \u0111\u1eb7c c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c s\u1ea3n xu\u1ea5t sau khi thi\u00eau k\u1ebft.<\/p>\n","protected":false},"excerpt":{"rendered":"

Qua nghi\u00ean c\u1ee9u, ng\u01b0\u1eddi ta th\u1ea5y r\u1eb1ng c\u00e1c th\u00e0nh ph\u1ea7n ch\u00ednh trong gangue than l\u00e0 alumina v\u00e0 silica, v\u00e0 c\u00e1c h\u1ee3p ch\u1ea5t n\u00e0y th\u01b0\u1eddng \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng l\u00e0m nguy\u00ean li\u1ec7u th\u00f4 \u0111\u1ec3 s\u1ea3n xu\u1ea5t g\u1ed1m s\u1ee9.<\/p>\n","protected":false},"author":7,"featured_media":125373,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[852],"tags":[],"class_list":["post-125480","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-cong-nghiep-tin-tuc-vi"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/posts\/125480","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/users\/7"}],"replies":[{"embeddable":true,"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/comments?post=125480"}],"version-history":[{"count":0,"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/posts\/125480\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/media\/125373"}],"wp:attachment":[{"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/media?parent=125480"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/categories?post=125480"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.alpapowder.com\/vi\/wp-json\/wp\/v2\/tags?post=125480"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}